Revised structure of deacetyl-1,10-didehydrosalvinorin G

Zhongze Ma; David Y W Lee

doi:10.1016/j.tetlet.2007.05.179

Revised structure of deacetyl-1,10-didehydrosalvinorin G

Tetrahedron Lett. 2007 Jul 30;48(31):5461-5464. doi: 10.1016/j.tetlet.2007.05.179.

Authors

Zhongze Ma¹, David Y W Lee

Affiliation

¹ Bio-Organic and Natural Products Laboratory, McLean Hospital, Harvard Medical School, 115 Mill Street, Belmont, MA 02478.

Abstract

In comparison with the NMR data of salvinorin A and its 8-epimer, the published structure of deacetyl-1,10-didehydrosalvinorin G was revised to its 8-epimer. The stereochemistry of 8-epi-deacetyl-1,10-didehydrosalvinorin G was further confirmed by NOESY and chemical synthesis.

Abstract

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